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(5.2- 12)

where k is the photon wave number (k Eg =h c). The symbol !! calls for the double factorial of its argument, which for the case of l 2 and 2l 1 5 would be the product of the odd integers: 5!! 5 3 1 15. The reduced transition probability B(l, Ii , p ! If , p) is the matrix element for the reduced nuclear wave functions (i.e., summed over magnetic orientations) and the multipole operator (either electric or magnetic in character),

Summary

102 103 104

The equations for the individual P , Q and R subband branches are the same as those for linear molecules In order to distinguish between different subband branches, one uses the superscript P and R for the corresponding A K selection rule, eg, pQ~ll(J") for a Q-branch transition with AK = 1 The Q-branches may stand out against the other wide spread branch lines This is true of our example of the CH3I spectrum, which exhibits several perpendicular bands (see Fig 43-8) This spectrum also shows the line intensity alteration in the Q branches as a result of spin statistics So far we have neglected rotation-vibration interaction The rotational energy levels in a degenerate vibrational state of a symmetric top with a threefold or higher symmetry axis receive a contribution from Coriolis coupling.

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